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zero-point vibrational energy

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  • Zero-point energy — is the lowest possible energy that a quantum mechanical physical system may have; it is the energy of its ground state. All quantum mechanical systems undergo fluctuations even in their ground state and have an associated zero point energy, a… …   Wikipedia

  • Zero-point field — In quantum field theory, the zero point field is the lowest energy state of a field, i.e. its ground state, which is non zero. [cite book | last = Gribbin | first = John | title = Q is for Quantum An Encyclopedia of Particle Physics | publisher …   Wikipedia

  • zero-point energy — /zear oh poynt /, Physics. energy in a substance at the temperature of absolute zero. [1930 35] * * * Vibrational energy retained by molecules even at a temperature of absolute zero. Since temperature is a measure of the intensity of molecular… …   Universalium

  • Zero-phonon line and phonon sideband — The zero phonon line and the phonon sideband jointly constitute the line shape of individual light absorbing and emitting molecules (chromophores) embedded into a transparent solid matrix. When the host matrix contains many chromophores, each… …   Wikipedia

  • Internal energy — In thermodynamics, the internal energy of a thermodynamic system, or a body with well defined boundaries, denoted by U , or sometimes E , is the total of the kinetic energy due to the motion of molecules (translational, rotational, vibrational)… …   Wikipedia

  • Quantum chemistry composite methods — are ab initio post Hartree Fock methods in computational chemistry that aim for high accuracy by combining the results of several calculations. They combine methods with a high level of theory and a small basis set with methods that employ lower… …   Wikipedia

  • analysis — /euh nal euh sis/, n., pl. analyses / seez /. 1. the separating of any material or abstract entity into its constituent elements (opposed to synthesis). 2. this process as a method of studying the nature of something or of determining its… …   Universalium

  • spectroscopy — spectroscopist /spek tros keuh pist/, n. /spek tros keuh pee, spek treuh skoh pee/, n. the science that deals with the use of the spectroscope and with spectrum analysis. [1865 70; SPECTRO + SCOPY] * * * Branch of analysis devoted to identifying… …   Universalium

  • Heat capacity — Thermodynamics …   Wikipedia

  • Thermodynamic temperature — is the absolute measure of temperature and is one of the principal parameters of thermodynamics. Thermodynamic temperature is an “absolute” scale because it is the measure of the fundamental property underlying temperature: its null or zero point …   Wikipedia

  • Temperature — This article is about the thermodynamic property. For other uses, see Temperature (disambiguation). A map of global long term monthly average surface air temperatures i …   Wikipedia

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